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[1]崔咪芬,乔旭.PCl_3氧化反应的宏观动力学[J].南京工业大学学报(自然科学版),1994,16(02):55-60.
 Cui Mifen,Qiao Xu(Department of Chemical Engineering,Nanjing Institute of Chemical Technology0009,et al.STUDY ON APPARENT KINETICS OF OXIDATION OF PHOSPHORUS TRICHLORIDE BY OXYGEN[J].Journal of NANJING TECH UNIVERSITY(NATURAL SCIENCE EDITION),1994,16(02):55-60.
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PCl_3氧化反应的宏观动力学()
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《南京工业大学学报(自然科学版)》[ISSN:1671-7627/CN:32-1670/N]

卷:
16
期数:
1994年02期
页码:
55-60
栏目:
出版日期:
1994-04-20

文章信息/Info

Title:
STUDY ON APPARENT KINETICS OF OXIDATION OF PHOSPHORUS TRICHLORIDE BY OXYGEN
作者:
崔咪芬 乔旭
南京化工学院化学工程系
Author(s):
Cui Mifen; Qiao Xu(Department of Chemical Engineering Nanjing Institute of Chemical Technology210009 Nanjing China)
关键词:
宏观动力学 PCl3 POCl3 氧化反应
Keywords:
apparent kinetics phosphorus trichloride phosphorus oxychloride oxidation
分类号:
O643.134
摘要:
针对PCl3氧气直接氧化生成POCl3的气液相反应,采用鼓泡搅拌釜,通过改变通氧速率、反应温度、搅拌转速和氧初始分压,测定了反应液中PCl3浓度随反应时间的变化关系,经数据处理和分析判别,确定了在实验操作范围内反应过程的宏观动力学类型,建立了相应的宏观动力学模型,求得了有关模型参数。
Abstract:
For a gas-liquid reaction (g) +PCl3 (1)→POCl3 (1), the variations of concentrationof phosphorus trichloride with reaction time were measured in a stirred bubble bank reactor by changingoxygen introduction rate, reaction temperature, agitator speed and ini

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更新日期/Last Update: 1900-01-01