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[1]徐晓容,李丹,景文珩,等.溶胶-凝胶法制备Si掺杂TiO2超滤膜[J].南京工业大学学报(自然科学版),2014,36(03):67-71.[doi:10.3969/j.issn.1671-7627.2014.03.013]
 XU Xiaorong,LI Dan,JING Wenheng,et al.Fabrication of Si-doped TiO2 ultrafiltration membranes by sol-gel process[J].Journal of NANJING TECH UNIVERSITY(NATURAL SCIENCE EDITION),2014,36(03):67-71.[doi:10.3969/j.issn.1671-7627.2014.03.013]
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溶胶-凝胶法制备Si掺杂TiO2超滤膜()
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《南京工业大学学报(自然科学版)》[ISSN:1671-7627/CN:32-1670/N]

卷:
36
期数:
2014年03期
页码:
67-71
栏目:
出版日期:
2014-05-20

文章信息/Info

Title:
Fabrication of Si-doped TiO2 ultrafiltration membranes by sol-gel process
文章编号:
1671-7627(2014)03-0067-05
作者:
徐晓容李丹景文珩范益群
南京工业大学 化学化工学院 材料化学工程国家重点实验室,江苏 南京 210009
Author(s):
XU XiaorongLI DanJING WenhengFAN Yiqun
State Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemistry and Chemical Engineering,Nanjing Tech University,Nanjing 210009,China
关键词:
Si掺杂 TiO2超滤膜 溶胶-凝胶
Keywords:
Si-doped TiO2 ultrafiltration membrane sol-gel
分类号:
TQ028.8
DOI:
10.3969/j.issn.1671-7627.2014.03.013
文献标志码:
A
摘要:
以钛酸四丁酯为Ti源、正硅酸乙酯为Si源、乙酰丙酮为螯合剂、HNO3为催化剂、P123为模板剂,采用溶胶-凝胶法制备Si掺杂的TiO2介孔材料。利用低温N2吸附-脱附法、X线衍射仪(XRD)、透射电子显微镜(TEM)等考察Si掺杂量对TiO2材料的微观结构及晶体结构的影响。结果表明:Si的最佳掺杂量n(Si)/n(Ti)=0.05,且Si的引入阻碍了TiO2材料组装孔的坍塌,抑制了TiO2材料的晶型转变温度,同时提高了TiO2材料的比表面积。选用最佳Si掺杂量溶胶为涂膜液,通过过滤实验表征,3次涂膜后的TiO2片式膜的纯水通量为3.6×10-5 L/(m2·h·Pa),截留相对分子质量为19 900 。
Abstract:
Using tetrabutyl titanate and tetraethyl silicate as precursors,HNO3 as catalyst and P123 as template,mesoporous TiO2 materials were synthesized by sol-gel route.The influence of Si/Ti molar ratio on the microstructure of TiO2 materials was investigated by N2 adsorption-desorption isotherm analysis,X-ray diffraction(XRD),and transmission electron microscopy(TEM).Results showed that the best n(Si)/n(Ti)=0.05,the Si-doping in the titanium inhibited the TiO2 phase transformation and the rapid growth of the crystals,and prevented the collapse of the assembled pores during the calcination process with the increasing of specific surface area.The Si concentration of 5% was used to fabricate the plate of TiO2 ultrafiltration membrane.Filtration experiments showed that,after the three spin-coating,the pure water flux of TiO2 ultrafiltration membrane was 3.6×10-5L/(m2·h·Pa)with a cut-off molecular weight of 19 900.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2013-05-14
基金项目:国家自然科学基金(21176116); 国家高技术研究发展计划(863计划)(2012AA03A606); 江苏省自然科学基金(BK2011801); 江苏省高校自然科学基金(10KJB530003)
作者简介:徐晓容(1988—),女,江苏海安人,硕士,主要研究方向为陶瓷膜材料; 景文珩(联系人),研究员,E-mail:jingwh@njtech.edu.cn..
更新日期/Last Update: 2014-05-20