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[1]曹栋泳,沈国平,郦斌,等.3-对甲基苯基-4-氨基-5-(2-喹啉基)-1,2,4-三氮唑及其Fe(Ⅱ)配合物的合成[J].南京工业大学学报(自然科学版),2014,36(03):115-118.[doi:10.3969/j.issn.1671-7627.2014.03.022]
 CAO Dongyong,SHEN Guoping,LI Bin,et al.Syntheses of 3-(p-methylphenyl)-4-amino-5-(2-quinolyl)-1,2,4-triazole and its Fe(II)complex[J].Journal of NANJING TECH UNIVERSITY(NATURAL SCIENCE EDITION),2014,36(03):115-118.[doi:10.3969/j.issn.1671-7627.2014.03.022]
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3-对甲基苯基-4-氨基-5-(2-喹啉基)-1,2,4-三氮唑及其Fe(Ⅱ)配合物的合成()
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《南京工业大学学报(自然科学版)》[ISSN:1671-7627/CN:32-1670/N]

卷:
36
期数:
2014年03期
页码:
115-118
栏目:
出版日期:
2014-05-20

文章信息/Info

Title:
Syntheses of 3-(p-methylphenyl)-4-amino-5-(2-quinolyl)-1,2,4-triazole and its Fe(II)complex
文章编号:
1671-7627(2014)03-0115-04
作者:
曹栋泳沈国平郦斌沈旋朱敦如
南京工业大学 化学化工学院,江苏 南京 210009
Author(s):
CAO DongyongSHEN GuopingLI BinSHEN XuanZHU Dunru
College of Chemistry and Chemical Engineering,Nanjing Tech University,Nanjing 210009,China
关键词:
三氮唑 Fe(Ⅱ)配合物 光谱表征
Keywords:
124-triazole Fe(Ⅱ)complex spectral characterization
分类号:
TQ028.8
DOI:
10.3969/j.issn.1671-7627.2014.03.022
文献标志码:
A
摘要:
根据分子设计的原理,以2-喹啉甲酰肼为起始原料,经三步反应合成了1个新的三取代-1,2,4-三氮唑配体3-对甲基苯基-4-氨基-5-(2-喹啉基)-1,2,4-三氮唑(L),产率为74.7%,配体L经熔点、红外光谱(FT-IR)、核磁共振氢谱(1H NMR)、电喷雾质谱(ESI-MS)和元素分析表征。用配体L与Fe(Ⅱ)离子反应,制备了配合物[FeL2(NCS)2](1),对其进行了红外和元素分析表征。
Abstract:
Based on the principle of molecular design,a new trisubstituted-1,2,4-triazole ligand,3-(p-methylphenyl)-4-amino-5-(2-quinolyl)-1,2,4-triazole(L)was synthesized from 2-quinolylhydrazine by a three-step organic reaction with a yield of 74.7%.The ligand L was characterized by melting point,Fourier transform-infrared spectroscopy(FT-IR),1H-nuclear magnetic resonance(1H NMR),electrospray ionization mass spectrometry(ESI-MS),and elemental analysis.And by the ligand L and Fe(Ⅱ)complex,[FeL2(NCS)2](1),was also synthesized and characterized by FT-IR and elemental analysis.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2013-05-09
基金项目:国家自然科学基金(20771059,21171093); 江苏省普通高校研究生科研创新计划(CXZZ12_0436); 材料化学工程国家重点实验室开放基金(KL11-03)
作者简介:曹栋泳(1990—),男,江苏南通人,硕士,主要研究方向为配位化学; 朱敦如(联系人),教授,E-mail:zhudr@njtech.edu.cn..
更新日期/Last Update: 2014-05-20