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[1]李红月,王宝才,俞娟,等.聚酰亚胺薄膜表面银颗粒的制备及化学镀铜效果[J].南京工业大学学报(自然科学版),2016,38(02):114-118.[doi:10.3969/j.issn.1671-7627.2016.02.021]
 LI Hongyue,WANG Baocai,YU Juan,et al.Preparation of silver particles on polyimide films for chemical copper planting[J].Journal of NANJING TECH UNIVERSITY(NATURAL SCIENCE EDITION),2016,38(02):114-118.[doi:10.3969/j.issn.1671-7627.2016.02.021]
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聚酰亚胺薄膜表面银颗粒的制备及化学镀铜效果()
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《南京工业大学学报(自然科学版)》[ISSN:1671-7627/CN:32-1670/N]

卷:
38
期数:
2016年02期
页码:
114-118
栏目:
出版日期:
2016-04-10

文章信息/Info

Title:
Preparation of silver particles on polyimide films for chemical copper planting
文章编号:
1671-7627(2016)02-0114-05
作者:
李红月王宝才俞娟王晓东黄培
南京工业大学 化工学院,江苏 南京 210009
Author(s):
LI HongyueWANG BaocaiYU JuanWANG XiaodongHUANG Pei
College of Chemical Engineering,Nanjing Tech University,Nanjing 210009,China
关键词:
聚酰亚胺 化学镀铜
Keywords:
polyimide silver copper electroless copper planting
分类号:
TQ153.14
DOI:
10.3969/j.issn.1671-7627.2016.02.021
文献标志码:
A
摘要:
为了使聚酰亚胺(PI)薄膜表面具有良好的活性,采用NaOH溶液对PI薄膜进行化学改性,在PI薄膜表面制备金属Ag微粒,然后进行化学镀铜。采用傅里叶变换衰减全反射红外光谱仪(ATR-FT-IR)、X线衍射仪(XRD)、扫描电子显微镜(SEM)和电阻测试仪等对复合薄膜的结构和性能进行表征,并讨论AgNO3溶液处理时间对Cu层的影响。结果表明:PI薄膜表面在NaOH溶液中发生水解,在AgNO3溶液中实现Na+和Ag+间的离子交换,经过NaBH4还原,在PI薄膜表面形成Ag微粒,该Ag微粒可以引导化学镀铜反应的发生。试验中,控制其他条件不变,在2 g/L的AgNO3溶液中离子交换30 min可以制得形貌和电性能良好的PI/Cu复合薄膜,方块电阻可低至0.585 Ω。
Abstract:
The polyimide(PI)film was modified with NaOH solution to obtain the metal silver particles on the surface for chemical copper plating with the improved activity of PI film surface.The structures and properties of composite film,as well as the effects of AgNO3 solution on the copper layer were characterized by Fourier transform attenuated total reflection infrared spectrum(ATR-FT-IR),X-ray diffractometer(XRD),scanning electron microscope(SEM),and four-point probe meter.Results showed that the surface of PI film was hydrolyzed in NaOH solution with the ion exchange between Na+ and Ag+ happened in AgNO3 solution,and the Ag particles were formed on the surface after reduced by NaBH4, inducing the reaction of copper plating.The resistance of PI/Cu composite film with fine morphology and electrical property could be as low as 0.585 Ω under the condition of the ion exchange for 30 min in 2 g/L AgNO3 solution with invariant other conditions.

参考文献/References:

[1] 颜红侠,梁国正,马晓燕,等.聚酰亚胺无机纳米杂化材料[J].高分子通报,2003(6):28.
[2] 蒋英,阙正波,张竞,等.聚酰亚胺薄膜表面水解动力学研究[J].绝缘材料,2009(2):52.
[3] 秦志英,王为.聚酰亚胺表面钯微粒的制备及化学镀铜效果[J].
  材料保护,2012,45(11):45.
[4] 董云飞,蒋里锋,俞娟,等.化学还原法制备聚酰亚胺/银复合薄膜[J].高分子材料科学与工程,2013,29(6):14.
[5] 于倩倩.基于离子交换技术的聚酰亚胺表层无机功能化复合薄膜的制备及其微结构与性能研究[D].北京:北京化工大学,2011.
[6] LEE K W,VIEHBECK A.Wet-process surface modification of dielectric polymers:adhesion enhancement and metallization[J].IBM journal of research and development,1994,38(4):457.
[7] SOUTHWARD R E,THOMPSON D W.Metal-polyimide nanocomposite films:single-stage synthesis of silvered polyimide films prepared from silver(I)complexes and BPDA/4,4’-ODA[J].Chemistry of materials,2004,16(7):1277.
[8] MATSUMURA Y,ENOMOTO Y,TSURUOKA T,et al.Fabrication of copper damascene patterns on polyimide using direct metallization on trench templates generated by imprint lithography[J].Langmuir,2010,26(14):12448.
[9] HASEGAWA M,HORIE K.Photophysics,photochemistry,and optical properties of polyimides[J].Progress in polymer science,2001,26(2):259.
[10] AKAMATSU K,IKEDA S,NAWAFUNE H,et al.Direct patterning of copper on polyimide using ion exchangeable surface templates generated by site-selective surface modification[J].Journal of the American chemical society,2004,126(35):10822.

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备注/Memo

备注/Memo:
收稿日期:2015-05-07
作者简介:李红月(1989—),女,河南安阳人,硕士,主要研究方向为功能高分子材料; 黄培(联系人),教授,E-mail:phuang@njtech.edu.cn.
引用本文:李红月,王宝才,俞娟,等.聚酰亚胺薄膜表面银颗粒的制备及化学镀铜效果[J].南京工业大学学报(自然科学版),2016,38(2):114-118..
更新日期/Last Update: 2016-03-20